添加生物质炭对红壤性水稻土Cd2+吸附解吸特性的影响
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胡世民(1996-),男,硕士研究生,主要从事土壤重金属污染修复研究。E-mail:981660338@qq.com

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S158;X53

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国家重点研发计划项目(2016YFD0800306)


Effects of Biochar Amendment on Adsorption and Desorption Characteristics of Cd2+ in Red Paddy Soil
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    摘要:

    为探讨生物质炭对红壤性水稻土中镉(Cd)元素吸附解吸特性的影响,采用一次平衡法研究添加生物质炭后Cd2+在红壤性水稻土中的吸附动力学、等温吸附和解吸过程。结果表明:施用CK (0 t/hm2)、A10(10 t/hm2)、A20(20 t/hm2)、A30(30 t/hm2)和A40(40 t/hm2)生物质炭后,红壤性水稻土对Cd2+的吸附过程是以化学吸附为主、非均匀的多表面吸附。施用CK (0 t/hm2)、A10(10 t/h2)、A20(20 t/hm2)、A30(30 t/hm2)和A40(40 t/hm2)生物质炭处理的最大吸附量和最大解吸量分别为2 933~3 346 mg/kg和171~192 mg/kg。添加生物质炭可以提高红壤性水稻土对Cd2+的吸附固持能力,同时增强土壤对外源Cd2+的缓冲能力。生物质炭添加量对红壤性水稻土的吸附解吸能力的改良效果具体表现为:A30 > A40 > A20 > A10。高剂量的生物质炭处理使土壤吸附点位饱和,生物质炭吸附能力相对降低。因此,添加30 t/hm2生物质炭是一种有效预防和治理红壤性水稻土镉污染的措施。

    Abstract:

    In order to investigate the effects of biochar on the adsorption and desorption characteristics of cadmium (Cd) elements, the adsorption kinetics, isothermal adsorption and desorption of Cd2+ in red soil paddy soils amended with biochar were studied by a primary equilibrium method. The results showed that after applying biochar of CK (0 t/hm2), A10 (10 t/hm2), A20 (20 t/hm2), A30 (30 t/hm2) and A40 (40 t/hm2), the adsorption of Cd2+ in red paddy soil was dominated by chemical adsorption and heterogeneous multi-surface adsorption. The maximum contents of adsorption and desorption of each treatment were between 2 933~3 346 mg/kg and 171~192 mg/kg, respectively. The biochar enhanced the adsorption and fixation capacity for Cd2+ in red paddy soil and improved the buffer capacity for Cd2+. The improvement of adsorption and desorption capacity in red paddy soil amended with biochar was shown as follows:A30 > A40 > A20 > A10. High addition of biochar could saturate the soil adsorption point. Therefore, the adsorption capacity of biochar was relatively low. In conclusion, addition of 30 t/hm2 biochar was the most reasonable measure.

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胡世民, 陈效民, 景峰, 杨之江, 刘巍, 温馨.添加生物质炭对红壤性水稻土Cd2+吸附解吸特性的影响[J].水土保持学报,2020,34(2):360~364,371

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  • 收稿日期:2019-08-15
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  • 在线发布日期: 2020-04-13
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